This work was performed, in part, at the Center for Nanoscale Materials, a US Department of Energy Office of Science User Facility, and supported by the US Department of Energy, Office of Science, under contract no. The MERF and CAMP Facilities are fully supported by the DOE Vehicle Technologies Program within the core funding of the Applied Battery Research (ABR) for Transportation Program. The NMC442 electrode was made by the Cell Analysis, Modelling, and Prototyping (CAMP) Facility and provided by B. The LiDFOB salt was produced at the US DOE Materials Engineering Research Facility (MERF) and provided by K. PNNL is operated by Battelle for the DOE under Contract DE-AC05-76RLO1830. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at PNNL. The SEM, EDX, XRD, XPS and computational calculations were conducted in the William R. This work was supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies of the US Department of Energy (DOE) through the Advanced Battery Materials Research (BMR) program (Battery500 Consortium) under contract no. Development of the Colle–Salvetti correlation-energy formula into a functional of the electron density. The calculation of small molecular interactions by the differences of separate total energies. (Gaussian Inc., Wallingford CT, 2009).īoys, S. Suppressed oxygen extraction and degradation of LiNi xMn 圜o zO 2 cathodes at high charge cut-off voltages. Lithium difluoro(oxalato)borate: A promising salt for lithium metal based secondary batteries? Electrochim. Effects of imide-orthoborate dual-salt mixtures in organic carbonate electrolytes on the stability of lithium metal batteries. Accurate determination of Coulombic efficiency for lithium metal anodes and lithium metal batteries. Dead lithium: mass transport effects on voltage, capacity, and failure of lithium metal anodes. Effect of lithium difluoro(oxalate)borate (LiDFOB) additive on the performance of high-voltage lithium-ion batteries. Suppression of aluminum corrosion by using high concentration LiTFSI electrolyte. Enhanced cycling stability of rechargeable Li–O 2 batteries using high-concentration electrolytes. Novel concentrated Li-based ether electrolyte for superior stability of metallic lithium anode. Oxidative-stability enhancement and charge transport mechanism in glyme-lithium salt equimolar complexes.
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